Stereochemical Studies. XVI. Deaminative Acetolyses of L-Valine and L-Valine Benzyl Ester

Vibrational spectroscopic studies of L,D-alternating valine peptides

Raman and infrared spectra of Boc-(L-Val-D-Val),-OMe [(LD-Val),], with n = 4, 6 and 8, were obtained in crystalline and solution states. Based on predictions from normal-mode calculations of a number of relevant singleand double-stranded p-helix conformations, structures were assigned for the three oligopeptides under the abovementioned conditions. In the crystalline state, all three oligopepti...

A non-planar peptide bond in L-seryl-L-valine.

The molecular structure of (I) is shown in Fig. 1. Bond lengths and angles are normal, but the unusual non-planarity of the peptide bond is quite evident. The associated torsion angle C1ÐC3ÐN2ÐC4 (!) is 157.37 (15) , a deviation from 180 that is superceded among small chiral peptides only by the 156.6 ! angle in N-(tert-butoxycarbonyl)-l-Pro-l-Leu benzyl ester (Sugino et al., 1978). Fig. 2(a) s...

Nutritional Feasibility of L-Valine Inclusion in Commercial Broiler Diets

Introduction The poultry industry has recently dealt with fluctuating spikes in the price of various feed ingredients. When the cost of protein-rich feed ingredients goes up, the reduction of dietary crude protein via the use of commercially available amino acids becomes an effective formulation strategy that can reduce diet costs, maintain broiler performance and not interfere with feed millin...

Decomposition of L-valine under nonthermal dielectric barrier discharge plasma.

L-Valine solutions in water and phosphate buffer were treated with nonthermal plasma generated by using a dielectric barrier discharge (DBD) device and the products generated after plasma treatments were characterized by (1)H NMR and GC-MS. Our results demonstrate that L-valine is decomposed to acetone, formic acid, acetic acid, threo-methylaspartic acid, erythro-methlyaspartic acid, and pyruvi...

Uptake of L-valyl-L-valine and glycylsarcosine by hamster jejunum in vitro.